- Sandwich Shop Restaurants, Pikeville
- Search & Rescue, Pikeville
- Secondary Schools, Pikeville
- Septic Tank Pumping & Cleaning, Pikeville - Septic Systems
- Septic Tanks & Septic Systems Contractors, Pikeville - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
- Septic Tanks & Systems, Pikeville - Wholesale, Dealers & Suppliers
- Sheet Metal Contractors, Pikeville - Sheet Metal Fabrication
- Sheet Metal Fabricators & Ductwork Contractors, Pikeville
- Shopping & Shopping Services, Pikeville
- Siding Contractors, Pikeville - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Signs, Pikeville
- Snacks & Desserts, Pikeville
- Social Clubs & Organizations, Pikeville
- Social Services & Welfare, Pikeville
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- Specialty Animal Services, Pikeville
- Specialty Communication Companies & Services, Pikeville
- Specialty Goods Storage, Pikeville
- Specialty Stores, Pikeville
- Sporting & Recreational Camps, Pikeville
- State Government, Pikeville
- State Parks, Pikeville
- Steel & Metal Goods, Pikeville - Steel Distributors
- Stock Yards, Pikeville
- Stone & Rock Quarry, Pikeville - Gravel Pit, Shale, Granite, Limestone, Crushed Rock, etc
- Stone Setting Contractors, Pikeville
- Surveyor Services, Pikeville - Surveying Service
- Surveyors, Pikeville
- Swimming, Pikeville
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