- Salvage Yards, Madisonville - Auto, Motorcycle, Boat, Trucks, etc
- Sanctified Church, Madisonville
- Sandwich Shop Restaurants, Madisonville
- Savings & Loan Associations, Madisonville
- Savings Banks, Madisonville
- Scrap & Waste Machinery, Madisonville
- Scrap & Waste Materials, Madisonville
- Screens Doors & Windows, Madisonville
- Search & Rescue, Madisonville
- Secondary Schools, Madisonville
- Security Brokers & Dealers, Madisonville
- Senior Citizens Service & Health Organizations, Madisonville
- Septic Tank Installation & Repair, Madisonville - Septic Systems
- Septic Tank Pumping & Cleaning, Madisonville - Septic Systems
- Septic Tanks & Septic Systems Contractors, Madisonville - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
- Septic Tanks & Systems, Madisonville - Wholesale, Dealers & Suppliers
- Septic Tanks & Systems Contractors & Designers, Madisonville
- Shoe Stores, Madisonville - Mens, Womens & Kids Shoes
- Shopping & Shopping Services, Madisonville
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- Siding Contractors, Madisonville - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
- Social Security Counselors & Representatives, Madisonville
- Social Services & Welfare, Madisonville
- Special Interest Schools Or Instruction, Madisonville
- Speciality Food Stores, Madisonville
- Specialty Animal Services, Madisonville
- Specialty Stores, Madisonville
- Speech & Hearing Specialists, Madisonville
- Speech Pathologists, Madisonville - Speech & Language Therapy
- Sporting Goods Stores, Madisonville
- Staffing & Support Services, Madisonville
- State Government, Madisonville
- Stocks & Bond Brokers, Madisonville
- Storm Doors & Windows, Madisonville
- Storm Windows & Doors Installation & Repair, Madisonville
- Surveyor Services, Madisonville - Surveying Service
- Swimming Pool, Sauna & Spa Contractors, Madisonville
- Swimming Pools Contractors, Madisonville - Install Inground - Above Ground Pools
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