- Sand Gravel & Aggregate, Tazewell
- Sandwich Shop Restaurants, Tazewell
- Schools For The Physically Challenged, Tazewell
- Scrap & Waste Materials, Tazewell
- Screen Printing, Tazewell
- Secondary Schools, Tazewell
- Senior Citizens Service & Health Organizations, Tazewell
- Septic Tank Installation & Repair, Tazewell - Septic Systems
- Septic Tank Pumping & Cleaning, Tazewell - Septic Systems
- Septic Tanks & Septic Systems Contractors, Tazewell - Installation, Repair, Service, Cleaning & Pumping Septic Tanks
- Septic Tanks & Systems, Tazewell - Wholesale, Dealers & Suppliers
- Sheriff's Department, Tazewell
- Shopping & Shopping Services, Tazewell
- Siding Contractors, Tazewell - Vinyl Siding, Wood, Metal & Aluminum Siding Contractors - Installation & Repair
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- Signs, Tazewell
- Social Services & Welfare, Tazewell
- Societies & Foundation Associations, Tazewell
- Special Education & Care, Tazewell
- Speciality Food Stores, Tazewell
- Specialty Stores, Tazewell
- Speech & Hearing Specialists, Tazewell
- Speech Pathologists, Tazewell - Speech & Language Therapy
- Sporting Goods Stores, Tazewell
- Staffing & Support Services, Tazewell
- State Government, Tazewell
- Stone & Rock Quarry, Tazewell - Gravel Pit, Shale, Granite, Limestone, Crushed Rock, etc
- Surplus & Salvage Merchandise, Tazewell
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